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CAS RN: 15629-92-2 | Product Number: B1313

[1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride


Purity: >98.0%(T)
Synonyms:
  • [1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
  • Dichloro[1,3-bis(diphenylphosphino)propane]nickel(II)
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Product Number B1313
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight C__2__7H__2__6Cl__2NiP__2 = 542.05 
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 15629-92-2
Reaxys Registry Number 13876693
PubChem Substance ID 87564245
MDL Number

MFCD00015318

Specifications
Appearance Orange to Brown to Dark red powder to crystal
Purity(Chelometric Titration) min. 98.0 %
Purity(Argentometric Titration) min. 98.0 %
Properties (reference)
Melting Point 213 °C(dec.)
GHS
Pictogram Pictogram
Signal Word Danger
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H372 : Causes damage to organs through prolonged or repeated exposure.
H317 : May cause an allergic skin reaction.
H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H350 : May cause cancer.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P202 : Do not handle until all safety precautions have been read and understood.
P201 : Obtain special instructions before use.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P284 : Wear respiratory protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P308 + P313 : IF exposed or concerned: Get medical advice/ attention.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P304 + P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention.
P405 : Store locked up.
Related Laws:
ISHL Group 2 Substance under supervision
PRTR Law (New Specific Chemical) Specified Class 1 Designated Chemical Substances
Transport Information:
Application
Catalyst for Controlled Coupling Polymerization

References


Application
Kumada-Tamao-Corriu Coupling

References


PubMed Literature


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