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CAS RN: 64443-05-6 | Product Number: T2665

Tetrakis(acetonitrile)copper(I) Hexafluorophosphate


Purity: >97.0%(T)
Synonyms:
Documents:
5G
€88.00
15   ≥40 

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Product Number T2665
Purity / Analysis Method >97.0%(T)
Molecular Formula / Molecular Weight C__8H__1__2CuF__6N__4P = 372.72 
Physical State (20 deg.C) Solid
Storage Temperature <0°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive,Moisture Sensitive,Heat Sensitive
CAS RN 64443-05-6
Reaxys Registry Number 14262634
PubChem Substance ID 87561580
MDL Number

MFCD00064810

Specifications
Appearance White to Almost white powder to crystal
Purity(Potassium permanganate method) min. 97.0 %
Properties (reference)
Melting Point 160 °C(dec.)
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
HS Number 2926907090
Application
Perfluoroalkylation using Perfluoro Acid Anhydrides

T0433, P0566, H0337, T2665

Reference


Application
Copper Catalyzed Asymmetric Conjugate Addition

T2665

References


Application
Catalytic Asymmetric Vinylogous Conjugate Addition of Unsaturated Butyrolactones to α,β-Unsaturated Thioamides

S0930,T2665

Reference


Application
Copper-catalyzed C―H Amidation of Unactivated Arenes

T2665

Typical Procedure:
To a stirred mixture of [Cu(CH3CN)4]PF6 (0.010 g, 0.026 mmol) and neocuproine (0.005 g, 0.024 mmol) in the arene (ca. 1 mL) is added N-tosyloxy-2,2,2-trichloroethylcarbamate (0.050 g, 0.138 mmol) and the mixture is allowed to stir at 140 °C for 8 h. The reaction mixture is cooled to room temperature, filtered through a pad of silica, washed with CH2Cl2, and the filtrate is concentrated under vacuum. The residue is purified by silica chromatography using 5–15% Et2O in hexanes to obtain the regioisomeric mixture of aminated arenes. The isomer ratio is determined by NMR using 1,3,5-trimethoxybenzene as a reference.

References


PubMed Literature


Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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