Sign up for free shipping on all website orders, no minimum required, and get exclusive coupons!
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 475571-19-8 | Product Number: D5368
(S)-2,4-Diphenyl-4,5-dihydrooxazole
×
![]()
×
Purity: >98.0%(GC)
Synonyms:
- (S)-Pheox
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|---|
| 1G |
$137.00
|
1 | Ships from Philadelphia the same day* | 1 |
|
|
| 5G |
$414.00
|
2 | 1 | 5 |
|
* Items in stock locally typically ship the same day of ordering. Items from Japan stock are able to ship from a US warehouse within 2 weeks after ordering. For additional estimated shipment times, please refer to the Shipping Simulation tool. Note: Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | D5368 |
Purity / Analysis Method 
|
>98.0%(GC) |
| Molecular Formula / Molecular Weight | C__1__5H__1__3NO = 223.28 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| Packaging and Container
|
1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 475571-19-8 |
| Reaxys Registry Number | 10428533 |
| PubChem Substance ID | 354335345 |
Specifications
| Appearance | White or Colorless to Light yellow powder to lump to clear liquid |
| Purity(GC) | min. 98.0 % |
| Optical purity(GC) | min. 98.0 ee% |
Properties (reference)
| Specific Rotation | -40° (C=1.02,CHCl3) |
GHS
Related Laws:
Transport Information:
| HS Number | 2934.99.4400 |
Application
(S)-Pheox: A Useful Chiral Reagent for Ligands and Synthetic Intermediates
(S)-Pheox, a chiral phenyl oxazoline ligand, is used for asymmetric syntheses as a chiral catalyst with a metal, such as Ru(II)-(S)-Pheox [R0196].1,2) (S)-Pheox is also used as a synthetic intermediate for chiral compounds.3,4)
References
- 1)Asymmetric Inter- and Intramolecular Cyclopropanation Reactions Catalyzed by a Reusable Macroporous-Polymer-Supported Chiral Ruthenium(II)/Phenyloxazoline Complex
- 2)Highly stereoselective Ru(II)-Pheox catalyzed asymmetric cyclopropanation of terminal olefins with succinimidyl diazoacetate
- 3)Mild and efficient one-pot synthesis of chiral β-chalcogen amides via 2-oxazoline ring-opening reaction mediated by indium metal
- 4)β-Amidoaldehydes via oxazoline hydroformylation
PubMed Literature
Product Articles
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.