Sign up for free ground shipping on all website orders, no minimum required, and get exclusive coupons!
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 84349-27-9 | Product Number: S0908
Sodium Bromodifluoroacetate
×
![]()
×
Purity: >98.0%(T)(HPLC)
Synonyms:
- Bromodifluoroacetic Acid Sodium Salt
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 5G |
$172.00
|
1 | 6 | ≥100 |
|
| 25G |
$420.00
|
Contact Us | Contact Us | 35 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | S0908 |
Purity / Analysis Method 
|
>98.0%(T)(HPLC) |
| Molecular Formula / Molecular Weight | C__2BrF__2NaO__2 = 196.91 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Hygroscopic |
| CAS RN | 84349-27-9 |
| Reaxys Registry Number | 8229431 |
| PubChem Substance ID | 253660024 |
| MDL Number | MFCD04038355 |
Specifications
| Appearance | White to Almost white powder to crystaline |
| Purity(HPLC) | min. 98.0 area% |
| Purity(Ion exchange titration) | min. 98.0 % |
Properties (reference)
| Solubility in water | Soluble |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing. P363 : Wash contaminated clothing before reuse. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. |
Related Laws:
Transport Information:
| HS Number | 2915.90.5050 |
Application
Difluorocarbene Precursor
Experimental procedure: to a solution of 1,1-diphenylethylene (181.3 mg, 1.0 mmol) in diglyme (5 mL) is added a diglyme solution (10 mL) of sodium bromodifluoroacetate (78 mg, 0.40 mmol) dropwise for 10 min at 150 °C. Then, the reaction mixture is stirred for 5 min at 150 °C. After cooling to r.t., the reaction is quenched with ice water (30 mL). The organic materials are extracted with hexane (4 × 50 mL) and the combined organic layers are washed with brine (200 mL) and dried (Na2SO4). After removal of the solvent under reduced pressure, the residue is purified by silica gel column chromatography (hexane:EtOAc=100:1) to give 1,1-difluoro-2,2-diphenylcyclopropane (231.6 mg, 99%) as a colorless solid.
References
- Sodium bromodifluoroacetate: a difluorocarbene source for the synthesis of gem-difluorocyclopropanes
PubMed Literature
Product Articles
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.