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A Soft Nucleophile for Palladium(0)-Catalyzed
Addition to Allylic Systems
No.106(April 2002)
The product 1 reacts with allylic acetate 2 as a soft nucleophile in the presence of a palladium(0) catalyst and afford 2-phenylsulfonyl (4E)-enoate 3, which followed by desulfonation leads to the construction of trans-4-enoate 4.
References
- 1)A stereocontrolled synthesis of trans-allylic amines
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