Maximum quantity allowed is 999
请选择数量
CAS RN: 7697-37-2 | 產品號碼: N0806
| 產品號碼 | N0806 |
| 分子式 / 分子量 | HNO__3 = 63.01 |
| 外觀與形狀（20°C） | Liquid |
儲存條件 
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| 應避免的情況 | Light Sensitive |
| CAS RN | 7697-37-2 |
| Reaxys-RN | 3587310 |
| Merck Index(14) | 6577 |
| MDL編號 | MFCD00011349 |
產品規格
| Appearance | Colorless clear liquid |
| Concentration(Neutralization titration) | min. 67.5 w/w% |
性質
| 沸點 | 121 °C |
| 比重 | 1.41 |
| 水溶性 | Completely miscible |
GHS
| 圖形表示 |
|
| 信號詞 | Danger |
| 危險性說明 | H330 : Fatal if inhaled. H314 : Causes severe skin burns and eye damage. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H304 : May be fatal if swallowed and enters airways. H272 : May intensify fire; oxidizer. H290 : May be corrosive to metals. |
| 防範說明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P220 : Keep/Store away from clothing/ combustible materials. P210 : Keep away from heat. P234 : Keep only in original container. P221 : Take any precaution to avoid mixing with combustibles. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P390 : Absorb spillage to prevent material damage. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P406 : Store in corrosive resistant container with a resistant inner liner. P405 : Store locked up. |
相關法規
| RTECS # | QU5900000 |
運輸資料
| UN編號 | UN2031 |
| 類別 | 8 / 5.1 |
| 包裝類別 | II |
| HS編碼* | 2808.00-000 |
Application
TCI Practical Example: Nitration Using Nitric Acid
-
Used Chemicals
-
Procedure
-
A solution of 3',4'-dimethoxyacetophenone (5.00 g, 27.7 mmol) in acetic acid (13 mL) was added dropwise to a solution of nitric acid (100 mL) and acetic acid (20 mL) at 0 °C. After stirring for 6 hours, the reaction mixture was poured into iced water (1000 mL) and the crystallized solid was filtered off. The solid was washed with ethanol to afford 1 (3.66 g, 58% yield) as a light yellow powder.
-
Experimenter’s Comments
-
The reaction mixture was monitored by TLC (dichloromethane:ethyl acetate = 18:1, Rf = 0.69) and UPLC.
-
Analytical Data
-
Compound 1
1H NMR (400 MHz, CDCl3); δ 7.61 (s, 1H), 6.76 (s, 1H), 3.98 (s, 6H), 2.50 (s, 3H).
-
Lead Reference
-
- Triggering a [2]Rotaxane Molecular Shuttle by a Photochemical Bond-Cleavage Strategy
考研文獻
產品介紹報導
產品文件 （部分產品的分析圖譜無法提供，敬請諒解。）
SDS
請選擇語言。
請求的SDS不可用。
如需更多幫助，請聯繫我們 。
產品規格
檢驗報告(CoA)及其他文檔
請輸入批號
輸入的批號不正確
示例 CoA
可下載CoA示例。注：該示例可能非最新批次的CoA。
目前沒有該產品的 CoA 示例。
分析圖譜
請輸入批號
輸入的批號不正確
很抱歉，您搜索的分析圖譜無法提供。