TCI Chemistry News
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July 2024
TCI offers an extensive catalog of over 30,000 high quality organic reagents suitable for benchtop-to-bulk chemistry. This issue covers our chemistry topics as follows:
- SpiroBpy-BPin: Ligand for meta-Selective Catalytic C-H Borylation
- Iridium Photoredox Catalyst with Highly Oxidizing Excited State
- Chiral Phosphine Ligands: Skewphos Derivatives
- Di-Boc Guanidinylation of Amine Using the Guanidinylating Agent

SpiroBpy-BPin: Ligand for meta-Selective Catalytic C-H Borylation
SpiroBpy-Bpin [B6552] is a catalytic C-H borylation ligand that exhibits excellent meta-selectivity for various substituted arenes. The application of meta-borylated arenes is expected in the future.

Iridium Photoredox Catalyst with Highly Oxidizing Excited State
[Ir(dFCF3ppy)2-(5,5'-dCF3bpy)]PF6 [B6451] is an iridium photoredox catalyst with highly oxidative excited states. Please take a look at the redox potential data (literature values) of our visible light redox catalysts.
Redox Potentials of Visible Light Photoredox Catalysts.

Chiral Phosphine Ligands: Skewphos Derivatives
Skewphos derivatives [P2852], [P2853], [P2854], [B6674] are chiral phosphine ligands with flexible skeletons. Their reactivity and selectivity depend on the electron density and steric hindrance of the aryl groups. Asymmetric hydrogenation of dehydroamino acids and α-aryl-β-alkyl acrylates has been reported.

Di-Boc Guanidinylation of Amine Using the Guanidinylating Agent
We are proud to present the di-Boc guanidinylation of 4-bromophenethylamine using 1-[N,N'-(di-Boc)amidino]pyrazole [B3619] as a guanidinylating agent.
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