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CAS RN: 12150-46-8 | Product Number: B2027

1,1'-Bis(diphenylphosphino)ferrocene


Purity: >96.0%(T)
Synonyms:
  • 1,1'-Ferrocenebis(diphenylphosphine)
Documents:
1G
$18.00
1   1   ≥20 
5G
$28.00
7   2   ≥20 
25G
$114.00
5   3   ≥20 

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Product Number B2027
Purity / Analysis Method >96.0%(T)
Molecular Formula / Molecular Weight C__3__4H__2__8FeP__2 = 554.39  
Physical State (20 deg.C) Solid
CAS RN 12150-46-8
PubChem Substance ID 87564906
MDL Number

MFCD00001422

Specifications
Appearance Light yellow to Brown powder to crystaline
Purity(Chelometric Titration) min. 96.0 %
Properties (reference)
Melting Point 182 °C(dec.)
Solubility in water Insoluble
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing.
P363 : Wash contaminated clothing before reuse.
P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/doctor if you feel unwell.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
Related Laws:
Transport Information:
HS Number 2931.90.6000
Application
Synthesis of Carbinols

Typical procedure: Under an air atmosphere, a Schlenk tube is charged with Cu(OAc)2·H2O (4.0 mg, 0.02 mmol), dppf (16.6 mg, 0.03 mmol), arylboronic acid (0.4 mmol), aldehyde (0.2 mmol), NaOAc (49.2 mg, 0.6 mmol), and toluene (3 mL) under ice-salt (-20 °C). The mixture is stirred for 0.5 h at room temperature, refluxed for 24 h, and then cooled in a Schlenk tube to room temperature. The mixture is extracted with ethyl acetate (4×5 mL), and the organic layers are washed with water. The organic layers are dried over MgSO4, concentrated, and purified by flash column chromatography on silica gel to give the desired product.

References


PubMed Literature


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