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CAS RN: 1335047-34-1 | Product Number: B6254

(4,4'-Di-tert-butyl-2,2'-bipyridine-κ2N1,N1')[bis[3,5-difluoro-2-(5-methyl-2-pyridinyl-κN)phenyl-κC1]]iridium Hexafluorophosphate


Purity: >90.0%(HPLC)
Synonyms:
  • (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[2-(2',4'-difluorophenyl)-5-methylpyridine]iridium(III) Hexafluorophosphate
  • [Ir(dF(Me)ppy)2(dtbbpy)]PF6
Documents:
200MG
$153.00
Contact Us 2   12  
1G
$459.00
Contact Us 1   ≥20 

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Product Number B6254
Purity / Analysis Method >90.0%(HPLC)
Molecular Formula / Molecular Weight C__4__2H__4__0F__1__0IrN__4P = 1013.98  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive
CAS RN 1335047-34-1
MDL Number

MFCD31619196

Specifications
Appearance Light yellow to Yellow powder to crystal
Purity(HPLC) min. 90.0 area%
Properties (reference)
Melting Point 360 °C
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P362 : Take off contaminated clothing and wash before reuse.
Related Laws:
Transport Information:
HS Number 2843.90.0000
Application
TCI Practical Example: The Intermolecular Hydroamination of the Unactivated Alkene and the Dialkylamine Catalyzed Using a Photoredox Catalyst

The Intermolecular Hydroamination of the Unactivated Alkene and the Dialkylamine Catalyzed Using a Photoredox Catalyst

Used Chemicals

Procedure

2,4,6-Triisopropylbenzenethiol (0.060 g, 0.25 mmol, 0.5 eq), piperidine (0.050 mL, 0.50 mmol, 1.0 eq), 4-methoxystyrene (0.10 mL, 0.75mmol, 1.5 eq), Ir[dF(Me)(ppy)2(dtbbpy)]PF6 (10 mg, 0.0099 mmol, 2.0 mol%) were dissolved in toluene (10 mL) at rt under N2. The mixture was placed at a distance of 2-3 cm from Blue LED lamp with a cooling fan. The yellow orange suspension was stirred at rt under visible light irradiation until the amine was completely consumed. After 12 h of irradiation, the reaction mixture was diluted with ethyl acetate (20 mL) and extracted with 1 mol/L HCl aq. (70 mL x 2). The combined aqueous layer was washed with diethyl ether (30 mL x 2), then neutralized with 2 mol/L NaOH aq. (78 mL) to pH 7 and then saturated sodium bicarbonate aq. (10 mL) was added to ensure slightly basic conditions. The aqueous layer was extracted with dichloromethane (50 mL x 3). The combined organic layer was dried over sodium sulfate (30 g) for about 30 minutes and then filtered. The solvent was removed in vacuo to give compound 1 as a colorless oil (39 mg, y. 35%).

Experimenter’s Comments

Toluene was degassed with nitrogen for 30 minutes before use.
Irradiation of visible light was performed with Kessil A160WE Tuna Blue 40Wx2.
The reaction mixture was maintained at rt by a cooling fan.
The reaction mixture was monitored by 1H NMR and GC.

Analytical Data

Compound 1

1H NMR (400 MHz, CDCl3); δ 7.12 (d, J = 7.8 Hz, 2H), 6.82 (d, J = 7.8 Hz, 2H), 3.78 (s, 3H), 2.79–2.75 (m, 2H), 2.56–2.49 (m, 6H), 1.46 (m, 4H), 1.25 (bs, 2H).

13C NMR (101 MHz, CDCl3); δ 157.82, 132.58, 129.57, 113.75, 61.64, 55.22, 54.51, 32.62, 25.90, 24.37.

Lead Reference

Other References


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