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CAS RN: 92220-65-0 | Product Number: D5744

Dichlorotetrakis[2-(2-pyridinyl)phenyl]diiridium(III)


Purity: >98.0%(HPLC)
Synonyms:
  • [(ppy)2IrCl]2
Documents:
200MG
$130.00
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1G
$448.00
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Product Number D5744
Purity / Analysis Method >98.0%(HPLC)
Molecular Formula / Molecular Weight C__4__4H__3__2Cl__2Ir__2N__4 = 1,072.10 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive
CAS RN 92220-65-0
Reaxys Registry Number 17830671
PubChem Substance ID 468591535
MDL Number

MFCD07784515

Specifications
Appearance Light orange to Yellow to Green powder to crystal
Purity(HPLC) min. 98.0 area%
NMR confirm to structure
Properties (reference)
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P362 : Take off contaminated clothing and wash before reuse.
Related Laws:
Transport Information:
HS Number 3815.12.0000
Application
Preparing for Iridium-Organic Unit of Photoredox-active MOF

A mixture of H2dcbpy [B3502] (2 mmol, 0.5 g) and Ir2(ppy)4Cl2 [D5744] (1 mmol, 1 g) is dissolved in CH3OH (100 mL). Excessive Na2CO3 is added to the reaction mixture and then heated to reflux under stirring for 5 h. After cooling to room temperature, the solvent is removed under rotary evaporation. Deionized water is added to dissolve the precipitation by stirring, and the complex is achieved by the addition of hydrochloric acid, and then filtered and dried (82% yield based on Ir).

References


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