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CAS RN: 16949-15-8 | Product Number: L0186
Lithium Borohydride (ca. 4mol/L in Tetrahydrofuran)
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Purity:
Synonyms:
- Lithium Tetrahydridoborate (ca. 4mol/L in Tetrahydrofuran)
- Lithium Tetrahydroborate (ca. 4mol/L in Tetrahydrofuran)
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 100ML |
$583.00
|
3 | 2 | ≥100 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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Supplemental Product Information:
100mL bottle of this product is attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".
| Product Number | L0186 |
| Molecular Formula / Molecular Weight | H__4BLi = 21.78 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| Packaging and Container | 100ML-DualSeal Bottle (View image) |
| CAS RN | 16949-15-8 |
| Reaxys Registry Number | 11536633 |
| PubChem Substance ID | 87558580 |
| Merck Index (14) | 5525 |
Specifications
| Appearance | Colorless to Brown clear liquid to cloudy liquid |
| Concentration(Gasburet method) | 9.5 to 11.5 w/w% |
Properties (reference)
| Flash point | -18 °C |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 : Harmful if swallowed. H314 : Causes severe skin burns and eye damage. H371 : May cause damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H351 : Suspected of causing cancer. H335 : May cause respiratory irritation. H225 : Highly flammable liquid and vapor. H260 : In contact with water releases flammable gases which may ignite spontaneously. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P223 : Do not allow contact with water. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground/bond container and receiving equipment. P231 + P232 : Handle under inert gas. Protect from moisture. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P201 : Obtain special instructions before use. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P335 + P334 : Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P402 + P404 : Store in a dry place. Store in a closed container. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN3399 |
| Class (DOT-AIR) | 4.3/3 |
| Packing Group (TCI-A) | I |
| HS Number | 2850.00.5000 |
Application
Reducing Agent
References
- Mixed solvents containing methanol as useful reaction media for unique chemoselective reductions within lithium borohydride
- Improved procedure for the reduction of N-acyloxazolidinones
- Regiospecific reduction of 5-benzylidene-2,4-thiazolidinediones and 4-oxo-2-thiazolidinethiones using lithium borohydride in pyridine and tetrahydrofuran
Application
Inorganic Hydride Used as A Hydrogen Sources of Fuel Cell
References
- Development of hydrogen storage for fuel cell generators. I: Hydrogen generation using hydrolysis of hydrides
- Hydrogen generation from hydrides in millimeter scale reactors for micro proton exchange membrane fuel cell applications
- Hydrogen desorption from LiBH4 destabilized by chlorides of transition metal Fe, Co, and Ni
PubMed Literature
Please visit the Pubchem page at this link.
Documents
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
C of A & Other Certificates
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Analytical Charts
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