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CAS RN: 674783-97-2 | Product Number: M1774
9-Mesityl-10-methylacridinium Perchlorate
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Purity: >98.0%(HPLC)
Synonyms:
- 10-Methyl-9-(2,4,6-trimethylphenyl)acridinium Perchlorate
Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 1G |
$152.00
|
2 | 2 | ≥100 |
|
| 5G |
$429.00
|
3 | Contact Us | ≥80 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | M1774 |
| Purity / Analysis Method | >98.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__2__3H__2__2ClNO__4 = 411.88 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 674783-97-2 |
| Reaxys Registry Number | 9678980 |
| PubChem Substance ID | 87559030 |
Specifications
| Appearance | Light yellow to Amber to Dark green powder to crystal |
| Purity(HPLC) | min. 98.0 area% |
| Purity(with Total Nitrogen) | min. 97.0 % |
Properties (reference)
| Solubility (soluble in) | Acetone |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H272 : May intensify fire; oxidizer. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P220 : Keep/Store away from clothing/ combustible materials. P210 : Keep away from heat. P221 : Take any precaution to avoid mixing with combustibles. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN1479 |
| Class (DOT-AIR) | 5.1 |
| Packing Group (TCI-A) | III |
| HS Number | 2933.99.7900 |
Application
Oxidant-Free Arene-Azole Cross-Coupling via [Acr+-Mes][ClO4-]
References
- Photo-induced oxidant-free oxidative C–H/N–H cross-coupling between arenes and azoles
Application
A Photocatalyst in Material Science and Synthetic Organic Chemistry
9-Mesityl-10-methylacridinium perchlorate is used as a photocatalyst for photoinduced electron transfer (PET) reactions in material science, and for photoredox catalytic organic reactions in synthetic organic chemistry.
References
- 9-Mesityl-10-methylacridinium: An Efficient Type II and Electron-Transfer Photooxygenation Catalyst
- Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System
- Organic synthetic transformations using organic dyes as photoredox catalysts (a review)
- Long-Lived Charge Separation and Applications in Artificial Photosynthesis (a review)
- The direct anti-Markovnikov addition of mineral acids to styrenes
Application
Selective Oxygenation using Effective Electron-Transfer Photocatalysts
References
- S. Fukuzumi, H. Kotani, K. Ohkubo, S. Ogo, N. V. Tkachenko, H. Lemmetyinen, J. Am. Chem. Soc. 2004, 126, 1600.
- H. Kotani, K. Ohkubo, S. Fukuzumi, J. Am. Chem. Soc. 2004, 126, 15999.
PubMed Literature
Articles/Brochures
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Safety Data Sheet (SDS)
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Specifications
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