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CAS RN: 26456-05-3 | Product Number: M1787
10-Methylacridinium Perchlorate
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Purity: >98.0%(N)
Synonyms:
Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 250MG |
$66.00
|
Contact Us | 2 | 7 |
|
| 1G |
$201.00
|
1 | 1 | 22 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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| Product Number | M1787 |
| Purity / Analysis Method | >98.0%(N) |
| Molecular Formula / Molecular Weight | C__1__4H__1__2ClNO__4 = 293.70 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 26456-05-3 |
| Reaxys Registry Number | 3647072 |
| PubChem Substance ID | 87559032 |
Specifications
| Appearance | Light yellow to Amber to Dark green powder to crystal |
| Purity(with Total Nitrogen) | min. 98.0 % |
Properties (reference)
| Melting Point | 241 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H272 : May intensify fire; oxidizer. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P220 : Keep/Store away from clothing/ combustible materials. P210 : Keep away from heat. P221 : Take any precaution to avoid mixing with combustibles. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN1479 |
| Class (DOT-AIR) | 5.1 |
| Packing Group (TCI-A) | III |
| HS Number | 2933.99.7900 |
Application
Baeyer–Villiger Oxidation with 10-Methylacridinium as an Organocatalyst
Typical Procedure:
Cyclobutanone (0.5 mmol) and 10-methylacridinium perchlorate (7.4 mg, 0.025 mmol) are dissolved in CH3CN (1 mL). Hydrogen peroxide (68 µL, 30% solution in water, 0.6 mmol) is added and the mixture is irradiated with a 450 W high-pressure mercury lamp in a Pyrex® flask (λ>320 nm) at room temperature for 20 h. The course of the reaction is monitored by TLC. After completion of the reaction, solvent is evaporated in vacuum. Purification of the residue by column chromatography (silica gel, ethyl acetate/petroleum ether gradient) yields the corresponding lactone.
Cyclobutanone (0.5 mmol) and 10-methylacridinium perchlorate (7.4 mg, 0.025 mmol) are dissolved in CH3CN (1 mL). Hydrogen peroxide (68 µL, 30% solution in water, 0.6 mmol) is added and the mixture is irradiated with a 450 W high-pressure mercury lamp in a Pyrex® flask (λ>320 nm) at room temperature for 20 h. The course of the reaction is monitored by TLC. After completion of the reaction, solvent is evaporated in vacuum. Purification of the residue by column chromatography (silica gel, ethyl acetate/petroleum ether gradient) yields the corresponding lactone.
References
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Specifications
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