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CAS RN: 100-63-0 | Product Number: P0183
Phenylhydrazine
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Purity: >98.0%(GC)(T)
Synonyms:
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 25G |
$24.00
|
5 | 3 | ≥100 |
|
| 100G |
$38.00
|
7 | 8 | 38 |
|
| 500G |
$113.00
|
7 | 1 | ≥100 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | P0183 |
| Purity / Analysis Method | >98.0%(GC)(T) |
| Molecular Formula / Molecular Weight | C__6H__8N__2 = 108.14 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive |
| CAS RN | 100-63-0 |
| Reaxys Registry Number | 606080 |
| PubChem Substance ID | 87574432 |
| SDBS (AIST Spectral DB) | 561 |
| Merck Index (14) | 7293 |
| MDL Number | MFCD00007573 |
Specifications
| Appearance | White or Colorless to Orange to Green powder to lump to clear liquid |
| Purity(GC) | min. 98.0 % |
| Purity( Potassium iodate Method) | min. 98.0 % |
Properties (reference)
| Melting Point | 19 °C |
| Flash point | 88 °C |
| Specific Gravity (20/20) | 1.10 |
| Refractive Index | 1.61 |
| Degree of solubility in water | 145 g/l 25 °C |
| Solubility (miscible with) | Ether, Alcohol, Benzene, Chloroform |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H310 : Fatal in contact with skin. H301 + H331 : Toxic if swallowed or if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H341 : Suspected of causing genetic defects. H350 : May cause cancer. H400 : Very toxic to aquatic life. H227 : Combustible liquid. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P270 : Do not eat, drink or smoke when using this product. P262 : Do not get in eyes, on skin, or on clothing. P202 : Do not handle until all safety precautions have been read and understood. P260 : Do not breathe mist or vapours. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P201 : Obtain special instructions before use. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P272 : Contaminated work clothing must not be allowed out of the workplace. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 : Collect spillage. P307 + P311 : IF exposed: Call a POISON CENTER or doctor/ physician. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P302 + P350 + P310 : IF ON SKIN: Gently wash with plenty of soap and water. Immediately call a POISON CENTER or doctor/ physician. P304 + P340 + P311 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
Related Laws:
| RTECS# | MV8925000 |
Transport Information:
| UN Number (DOT-AIR) | UN2572 |
| Class (DOT-AIR) | 6.1 |
| Packing Group (TCI-A) | II |
| HS Number | 2928.00.1500 |
Application
Reagent for anemia model
References
- Screening of toxic-haemolytic anaemia in laboratory rats: a model of phenylhydrazine-induced haemolysis
- J. Berger, Haematologia (Budap) 1985, 18, 193.
- The effect of macrocytosis on rat erythrocyte deformability during recovery from phenylhydrazine-induced anemia
- J. M. Norton, Biorheology 1990, 27, 21.
- Effect of Tectona grandis on phenylhydrazine-induced anaemia in rats
- Cardiac remodelling, blood chemistry, haematology and oxygen consumption of Atlantic cod, Gadus morhua L., induced by experimental haemolytic anaemia with phenylhydrazine
Application
Direct Radical Arylation of Unactivated Arenes Using Phenyl Hydrazine
Typical Procedure: KOt-Bu (0.101 g, 0.9 mmol, 3.0 eq.), aryl iodide (0.3 mmol, 1.0 eq.) and benzene (2.8 mL) are added into a flame dried Schlenk tube under argon atmosphere. Then a 0.15 M solution of phenylhydrazine (0.2 mL, 0.03 mmol, 0.1 eq.) in benzene is added to this heterogeneous reaction mixture over 6 h using a syringe pump at 100 °C. After complete addition, the reaction mixture is stirred for an additional 24 h at 100 °C. After that it is cooled to room temperature, quenched with water (4 mL) and subsequently extracted with ethyl acetate (3 x 20 mL). The combined organic phase is washed with brine (5 mL), dried over anhydrous Na2SO4, filtered and concentrated under vacuum. The crude product is purified by flash column chromatography using pentane or a 95:05 mixture of pentane/ethyl acetate as an eluent.
References
PubMed Literature
Product Articles
[Research Articles] Direct Radical Arylation of Unactivated Arenes Using Phenyl HydrazineProduct Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
C of A & Other Certificates
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Analytical Charts
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