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CAS RN: 79-20-9 | Product Number: S0300

Methyl Acetate [Standard Material for GC]


Purity: >99.5%(GC)
Synonyms:
  • Acetic Acid Methyl Ester
Documents:
5ML
$94.00
2   10   ≥20 

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Product Number S0300
Purity / Analysis Method >99.5%(GC)
Molecular Formula / Molecular Weight C__3H__6O__2 = 74.08  
Physical State (20 deg.C) Liquid
CAS RN 79-20-9
Reaxys Registry Number 1736662
PubChem Substance ID 87575824
SDBS (AIST Spectral DB) 2778
Merck Index (14) 6008
MDL Number

MFCD00008711

Specifications
Appearance Colorless clear liquid
Purity(GC) min. 99.5 %
Properties (reference)
Boiling Point 57 °C
Flash point -16 °C
Specific Gravity (20/20) 0.94
Refractive Index 1.36
Solubility in water Soluble
Degree of solubility in water 240 g/l   20 °C
Solubility (miscible with) Alcohol,Ether
Solubility (soluble in) Benzene,Acetone,Chloroform
GHS
Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H320 : Causes eye irritation.
H370 : Causes damage to organs.
H335 : May cause respiratory irritation.
H225 : Highly flammable liquid and vapor.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P307 + P311 : IF exposed: Call a POISON CENTER or doctor/ physician.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 : Store in a well-ventilated place. Keep cool.
P405 : Store locked up.
Related Laws:
RTECS# AI9100000
Transport Information:
UN Number (DOT-AIR) UN1231
Class (DOT-AIR) 3
Packing Group (TCI-A) II
HS Number 2915.39.9000
Application
Acetylation of Alcohols via Transesterification using Acetylating Reagents

S0300

References

  • 1)Transesterification/Acylation of Secondary Alcohols Mediated by N-Heterocyclic Carbene Catalysts
  • 2)Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
    • P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


PubMed Literature


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