text.skipToContent text.skipToNavigation

Maximum quantity allowed is 999

Please select the quantity

CAS RN: 635-46-1 | Product Number: T0113

1,2,3,4-Tetrahydroquinoline


Purity: >95.0%(GC)
Synonyms:
Documents:
25ML
$19.00
2   7   ≥20 
100ML
$36.00
1   5   9  
500ML
$118.00
Contact Us 2   Contact Us

* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.


Product Number T0113
Purity / Analysis Method >95.0%(GC)
Molecular Formula / Molecular Weight C__9H__1__1N = 133.19  
Physical State (20 deg.C) Liquid
Storage Temperature 0-10°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive,Heat Sensitive
CAS RN 635-46-1
Reaxys Registry Number 116149
PubChem Substance ID 87576121
SDBS (AIST Spectral DB) 3232
MDL Number

MFCD00006693

Specifications
Appearance White or Colorless to Yellow to Green powder to lump to clear liquid
Purity(GC) min. 95.0 %
Freezing point 11.0 to 20.0 °C
Properties (reference)
Melting Point 13 °C
Boiling Point 251 °C
Flash point 113 °C
Specific Gravity (20/20) 1.06
Refractive Index 1.59
Solubility in water Insoluble
Degree of solubility in water < 1 g/l   20 °C
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P362 : Take off contaminated clothing and wash before reuse.
Related Laws:
Transport Information:
HS Number 2933.49.7000
Application
Catalytic Formylation Using Tetrahydroisoquinoline

T0113

Experimental procedure:
4-Methoxyphenylboronic acid (20.0 mmol, 3.04 g) and glyoxylic acid monohydrate (21.0 mmol, 1.93 g) are placed in a flask. Acetonitrile (100 mL) is injected into the flask and then 1,2,3,4-tetrahydroquinoline (4.0 mmol, 0.5 mL) is added. The mixture is stirred at room temperature for 48 h exposed to air. After stirred for 48 h, the solvent is reduced in vacuo, and the residue is purified by column chromatography (SiO2, hexanes:EtOAc) to provide p-anisaldehyde (77% yield).

References


PubMed Literature


TCIMAIL
Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.

The requested SDS is not available.

Please Contact Us for more information.

Specifications
C of A & Other Certificates
Please enter Lot Number Incorrect Lot Number is entered
Analytical Charts
Please enter Lot Number Incorrect Lot Number is entered

The requested analytical chart is not available. Sorry for the inconvenience.

Other Documents