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CAS RN: 14694-95-2 | Product Number: T0931
Tris(triphenylphosphine)rhodium(I) Chloride
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Purity: >98.0%(T)
Synonyms:
- Chlorotris(triphenylphosphine)rhodium(I)
- Wilkinson Catalyst
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 1G |
$159.00
|
8 | 8 | ≥60 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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| Product Number | T0931 |
| Purity / Analysis Method | >98.0%(T) |
| Molecular Formula / Molecular Weight | C__5__4H__4__5ClP__3Rh = 925.23 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 14694-95-2 |
| Reaxys Registry Number | 14664394 |
| PubChem Substance ID | 87576749 |
| SDBS (AIST Spectral DB) | 5193 |
| Merck Index (14) | 9758 |
| MDL Number | MFCD00010016 |
Specifications
| Appearance | Orange to Brown to Dark red powder to crystal |
| Purity(Argentometric Titration) | min. 98.0 % |
| NMR | confirm to structure |
Properties (reference)
| Solubility in water | Insoluble |
| Solubility (soluble in) | Benzene, Toluene, dichloromethane, Chloroform |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. |
Related Laws:
Transport Information:
| HS Number | 2843.90.0000 |
Application
Trimethylsilylation of Alcohols using TMS Reagents
Reference
- Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
- P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.
Application
Wilkinson’s Catalyst: a Homogeneous Catalyst for Hydrogenation
References
- 1)Total synthesis of (+)-fusarisetin A
- 2)Hydride Intermediates in Homogeneous Hydrogenation Reactions of Olefins and Acetylenes using Rhodium Catalysts
- 3)The preparation and properties of tris(triphenylphosphine)halogenorhodium(I) and some reactions thereof including catalytic homogeneous hydrogenation of olefins and acetylenes and their derivatives
Application
Rh-catalyzed Coupling Reaction between THF and Olefins
Reference
PubMed Literature
Documents
Product Articles
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Safety Data Sheet (SDS)
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Specifications
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