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CAS RN: 1208985-45-8 | Product Number: T2579
(1S,4S,5S)-4,7,7-Trimethyl-6-thiabicyclo[3.2.1]octane
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![(1S,4S,5S)-4,7,7-Trimethyl-6-thiabicyclo[3.2.1]octane](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "(1S,4S,5S)-4,7,7-Trimethyl-6-thiabicyclo[3.2.1]octane")
Purity: >98.0%(GC)
Synonyms:
- (+)-Isothiocineole
Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 1G |
$62.00
|
1 | 1 | Contact Us |
|
| 5G |
$311.00
|
Contact Us | 1 | Contact Us |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Specifications
| Appearance | Colorless to Almost colorless clear liquid |
| Purity(GC) | min. 98.0 % |
| Optical purity(GC) | min. 97.0 ee% |
| Specific rotation [a]20/D | +65.0 to +69.0 deg(neat) |
Properties (reference)
| Flash point | 79 °C |
| Specific Rotation | 67° (neat) |
| Refractive Index | 1.52 |
GHS
| Signal Word | Warning |
| Hazard Statements | H227 : Combustible liquid. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P403 + P235 : Store in a well-ventilated place. Keep cool. |
Related Laws:
Transport Information:
| HS Number | 2934.99.9001 |
Application
Chiral Sulfides for Optically Active Three-membered Rings
References
- 1) Practical and Highly Selective Sulfur Ylide Mediated Asymmetric Epoxidations and Aziridinations Using an Inexpensive, Readily Available Chiral Sulfide. Applications to the Synthesis of Quinine and Quinidine
- 2) Asymmetric synthesis of cyclopropyl phosphonates using chiral terpenyl sulfonium and selenonium ylidesw
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