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Maximum quantity allowed is 999
CAS RN: 64443-05-6 | Product Number: T2665
Tetrakis(acetonitrile)copper(I) Hexafluorophosphate
Purity: >97.0%(T)
Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
---|---|---|---|---|---|
5G |
$43.00
|
29 | 6 | ≥100 |
|
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Product Number | T2665 |
Purity / Analysis Method | >97.0%(T) |
Molecular Formula / Molecular Weight | C__8H__1__2CuF__6N__4P = 372.72 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Frozen (<0°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Air Sensitive,Moisture Sensitive,Heat Sensitive |
CAS RN | 64443-05-6 |
Reaxys Registry Number | 14262634 |
PubChem Substance ID | 87561580 |
MDL Number | MFCD00064810 |
Appearance | White to Almost white powder to crystal |
Purity(Potassium permanganate method) | min. 97.0 % |
NMR | confirm to structure |
Melting Point | 160 °C(dec.) |
Pictogram | |
Signal Word | Warning |
Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. |
HS Number | 2931.90.9052 |
Reference
- Perfluoroalkylation of Unactivated Alkenes with Acid Anhydrides as the Perfluoroalkyl Source
References
- Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones
- Searching for Practically Useful P-Chirogenic Phosphine Ligands
Reference
To a stirred mixture of [Cu(CH3CN)4]PF6 (0.010 g, 0.026 mmol) and neocuproine (0.005 g, 0.024 mmol) in the arene (ca. 1 mL) is added N-tosyloxy-2,2,2-trichloroethylcarbamate (0.050 g, 0.138 mmol) and the mixture is allowed to stir at 140 °C for 8 h. The reaction mixture is cooled to room temperature, filtered through a pad of silica, washed with CH2Cl2, and the filtrate is concentrated under vacuum. The residue is purified by silica chromatography using 5–15% Et2O in hexanes to obtain the regioisomeric mixture of aminated arenes. The isomer ratio is determined by NMR using 1,3,5-trimethoxybenzene as a reference.
References
Articles/Brochures
[Research Articles] Catalytic Asymmetric Vinylogous Conjugate Addition of Unsaturated Butyrolactones to α,β-Unsaturated Thioamides
[Research Articles] Copper-catalyzed C—H Amidation of Unactivated Arenes
Safety Data Sheet (SDS)
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Specifications
C of A & Other Certificates
Sample C of A
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