text.skipToContent text.skipToNavigation

Maximum quantity allowed is 999

Please select the quantity

CAS RN: 659-18-7 | Product Number: T3010

Tris(2,2,2-trifluoroethyl) Borate


Purity: >95.0%(T)
Synonyms:
  • Boric Acid Tris(2,2,2-trifluoroethyl) Ester
Documents:
1G
$92.00
Contact Us Contact Us ≥20 

* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.


Product Number T3010
Purity / Analysis Method >95.0%(T)
Molecular Formula / Molecular Weight C__6H__6BF__9O__3 = 307.91  
Physical State (20 deg.C) Liquid
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 659-18-7
Reaxys Registry Number 1714040
PubChem Substance ID 253659909
MDL Number

MFCD00093768

Specifications
Appearance Colorless to Almost colorless clear liquid
Purity(Neutralization titration) min. 95.0 %
Properties (reference)
Boiling Point 125 °C
Specific Gravity (20/20) 1.44
Refractive Index 1.30
GHS
Related Laws:
Transport Information:
HS Number 2920.90.5100
Application
Direct Amidation of Unprotected Amino Acids

T3010

Experimental procedure:
A solution of tris(2,2,2-trifluoroethyl) borate (3.0 mmol, 3.0 eq.) in CPME (1 mL) is added dropwise to a mixture of an unprotected amino acid (1.0 mmol, 1.0 eq.) and propylamine (3.0 mmol, 3.0 eq.) in CPME (1 mL) over 1 h at 80 °C or 125 °C. The resulting mixture is stirred for 5 - 15 h. Upon completion, the mixture is diluted with EtOAc or CH2Cl2 (3 mL) and water (0.5 mL). Amberlite IRA-743 and Amberlyst A-26(OH) are added and stirred for 30 min. The mixture is dried over MgSO4 and then filtered. The solids are washed with EtOAc (3 × 20 mL) and the product concentrated in vacuo. The volatile propylamine is removed in vacuo by the addition of CHCl3 to get the clean product.

References


PubMed Literature


Articles/Brochures

TCIMAIL
Documents
Safety Data Sheet (SDS) Search
Please select Language.

The requested SDS is not available.

• Please check that the Product Number you have entered is correct.

• If your information is correct and you are still not able to view the requested SDS,  please Contact Us for more information.

C of A & Other Certificates
Please enter Lot Number Incorrect Lot Number is entered
Other Documents