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CAS RN: 289706-46-3 | Product Number: T3597

4-[2,2,2-Trifluoro-1-[(trimethylsilyl)oxy]ethyl]morpholine


Purity: >95.0%(GC)
Synonyms:
Documents:
1G
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5G
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Product Number T3597
Purity / Analysis Method >95.0%(GC)
Molecular Formula / Molecular Weight C__9H__1__8F__3NO__2Si = 257.33 
Physical State (20 deg.C) Liquid
CAS RN 289706-46-3
Reaxys Registry Number 8622317
PubChem Substance ID 354335215
Specifications
Appearance Colorless to Almost colorless clear liquid
Purity(GC) min. 95.0 %
Properties (reference)
Flash point 78 °C
Refractive Index 1.41
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H227 : Combustible liquid.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P362 : Take off contaminated clothing and wash before reuse.
P403 + P235 : Store in a well-ventilated place. Keep cool.
Related Laws:
Transport Information:
HS Number 2934.99.9001
Application
Morpholine Derivative Usable for Introduction of a Trifluoromethyl Group

T3597

Trifluoromethylation of Aryl Iodides2): A Schlenk tube is charged with CuI (0.030 mmol, 5.7 mg), 1,10-phenanthroline (0.030 mmol, 5.4 mg) and CsF (0.60 mmol, 67.3 mg). The tube is evacuated and backfilled with argon, and then diglyme (0.60 mL), 4-nitroiodobenzene (0.30 mmol, 74.7 mg), and 1 (0.60 mmol, 154 mg) are added. The resulting reaction mixture is stirred at 80 °C for 24 h. After the reaction is complete, the mixture is cooled to room temperature, diluted with water, and extracted with ethyl acetate. The combined organic layers are washed with brine, dried over MgSO4, filtered, and the volatiles are removed in vacuo. The residue is purified by chromatography on silica gel to yield 4-nitrobenzotrifluoride (77% yield).

References


PubMed Literature


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