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Photoremovable DEACM Protecting Group

7-(Diethylamino)-4-(hydroxymethyl)coumarin (1) works as a photolabile protecting group of phosphoric acids and sulfonic acids and can be removed by irradiating at 300–450 nm.1) 1 is applied to photoinducing endosomal fusion by a caged phosphatidylinositol 3-phosphate in living cells2) and photo-control of RNA transcription by a caged adenosine triphosphate.3)

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