Sign up for free shipping on all website orders, no minimum required, and get exclusive coupons!
Users can now ask questions to the AI chatbot by clicking the chatbot icon in the bottom-right corner of the website.
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 26412-87-3 | Product Number: P0998
Pyridine - Sulfur Trioxide Complex
×
Purity: >95.0%(T)
Synonyms:
- Sulfur Trioxide - Pyridine Complex
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|---|
| 25G |
$101.00
|
2 | Ships from Philadelphia the same day* | 9 |
|
|
| 100G |
$226.00
|
2 | 1 | 22 |
|
|
| 500G |
$678.00
|
4 | 1 | 4 |
|
* Items in stock locally typically ship the same day of ordering. Items from Japan stock are able to ship from a US warehouse within 2 weeks after ordering. For additional estimated shipment times, please refer to the Shipping Simulation tool. Note: Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | P0998 |
Purity / Analysis Method 
|
>95.0%(T) |
| Molecular Formula / Molecular Weight | C__5H__5N·SO__3 = 159.16 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| CAS RN | 26412-87-3 |
| Reaxys Registry Number | 3704116 |
| PubChem Substance ID | 87575111 |
| MDL Number | MFCD00012437 |
Specifications
| Appearance | White to Light yellow powder to crystal |
| Purity(Ethanolysis Method) | min. 95.0 % |
| NMR | confirm to structure |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 : Harmful if swallowed. H314 : Causes severe skin burns and eye damage. H290 : May be corrosive to metals. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dusts or mists. P270 : Do not eat, drink or smoke when using this product. P234 : Keep only in original container. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P390 : Absorb spillage to prevent material damage. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P406 : Store in corrosive resistant container with a resistant inner liner. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN3261 |
| Class (DOT-AIR) | 8 |
| Packing Group (TCI-A) | III |
| HS Number | 2933.39.9200 |
Application
TCI Practical Example: Synthesis of the Aldehyde Utilizing the Parikh-Doering Oxidation
-
Used Chemicals
-
Procedure
-
To a solution of 3,5-dibenzyloxybenzyl alcohol (1.0 g, 3.1 mmol), N,N-diisopropylethylamine (2.7 mL, 15.6 mmol, 5.0 equiv), and DMSO (2.22 mL, 31 mmol, 10 equiv) in dichloromethane (10 mL) was added SO3·Py (1.49 g, 9.4 mmol, 3.0 equiv) at 0 °C. The reaction mixture was stirred at same temperature for 1 hour and quenched with Na2S2O3 aq. (20 mL) was added to the reaction mixture. The aqueous layer was extracted with dichloromethane (20 mL) and washed brine. The organic phase was concentrated under reduced pressure and the residue was purified by column chromatography (ethyl acetate:hexane = 0:1 - 1:1 on silica gel) to give 3,5-dibenzyloxybenzaldehyde as a white solid (850 mg，y. 85%).
-
Experimenter’s Comments
-
The reaction mixture was monitored by LC.
This reaction produces dimethyl sulfide, which gives off a bad smell. So that it is recommended to treat this reaction in a fume hood.
-
Analytical Data
-
3,5-dibenzyloxybenzaldehyde
1H NMR (270 MHz, CDCl3); δ 9.90 (s, 1H), 7.45-7.32 (m, 10H), 7.12 (d, J = 2.1 Hz, 2H), 6.87 (t, 1H, J = 2.1 Hz), 5.93 (s, 4H).
-
Lead Reference
-
- Bis(benzylamine) monomers: One-pot preparation and application in dendrimer scaffolds for removing pyrene from aqueous environments
-
Other References
-
- CO2-Catalyzed Oxidation of Benzylic and Allylic Alcohols with DMSO
Application
with DMSO or LiAlH4
References
- E. J. Corey, K. Achiwa, J. Org. Chem. 1969, 34, 3667.
- D. S. Watt, E. J. Corey, Tetrahedron Lett. 1972, 4651.
- J. R. Parikh, W. von E. Doering, J. Am. Chem. Soc. 1967, 89, 5505.
- Y. Hamada, T. Shioiri, Chem. Pharm. Bull. 1982, 30, 1921.
- D. A. Evans, J. Bartroli, Tetrahedron Lett. 1982, 23, 807.
PubMed Literature
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.