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Published TCIMAIL newest issue No.201
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CAS RN: 903592-98-3 | Product Number: B3235
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride
![Thumbnail of [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride](/medias/B3235.jpg?context=bWFzdGVyfHJvb3R8MTcxNTJ8aW1hZ2UvanBlZ3xhREptTDJoa05DODRPVE16TlRnNE56STVPRGcyTDBJek1qTTFMbXB3Wnd8MWVmYzZkNDZmOTI2NjIxOGQwNjQwNTA3YTU4MjE3OGMzMWE1MWEzNTgxMDUxZTNjY2I3ZTNmNjBmOTE2Zjg1NQ "[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride")
![Chemical Structure of [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride](/medias/B3235.jpg?context=bWFzdGVyfHJvb3R8NjAwMjd8aW1hZ2UvanBlZ3xhRGMzTDJnM09DODRPVEl3TVRBNU5ERTJORGM0TDBJek1qTTFMbXB3Wnd8MmViZjhhOTY5Y2ViZjEwYTk3Mzg3MWE0NDQxNTk3YmMwMWUxNDQ0ZWIxOGNhNTRjMzdlYWZjZDg2MDQzZDcwNg "[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride")
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![[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride](/_ui/responsive/theme-tci/images/missing_product_zoom.webp "[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride")
Purity: >98.0%(T)
Synonyms:
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 200MG |
46,00 €
|
Contact Us | Contact Us |
|
|
| 1G |
150,00 €
|
Ships within 12 weeks after ordering | Contact Us |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
Supplemental Product Information:
NiCl2(PPh3)IPr
| Product Number | B3235 |
Purity / Analysis Method 
|
>98.0%(T) |
| Molecular Formula / Molecular Weight | C__4__5H__5__1Cl__2N__2NiP = 780.48 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Moisture Sensitive |
| CAS RN | 903592-98-3 |
| PubChem Substance ID | 87561164 |
Specifications
| Appearance | Yellow to Amber to Dark red powder to crystal |
| Purity(Chelometric Titration) | min. 98.0 % |
| NMR | confirm to structure |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350 : May cause cancer. |
| Precautionary Statements | P260 : Do not breathe dust. P201 : Obtain special instructions before use. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P342 + P311 : If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P304 + P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
Related Laws:
Transport Information:
| HS Number | 2933299090 |
Application
Cross-Coupling Reaction of Grignard Regents with Aryl Thioethers
References
- Nickel–NHC-Catalyzed Cross-Coupling of 2-Methylsulfanylbenzofurans with Alkyl Grignard Reagents
- Ni-Catalyzed cross-coupling of aryl thioethers with alkyl Grignard reagents via C–S bond cleavage
Application
Kumada-Tamao-Corriu Cross-Coupling Reaction
References
- Synthesis and Structures of Nickel Halide Complexes Bearing Mono- and Bis-coordinated N-Heterocyclic Carbene Ligands, Catalyzing Grignard Cross-Coupling Reactions
Application
Controlled Polymerization Catalyst for Polythiophene
References
- C–H Functionalization Polycondensation of Chlorothiophenes in the Presence of Nickel Catalyst with Stoichiometric or Catalytically Generated Magnesium Amide
Documents
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