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CAS RN: 17185-29-4 | Product Number: C1383
Carbonylhydridotris(triphenylphosphine)rhodium(I)
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Purity:
Synonyms:
- Carbonyltris(triphenylphosphine)rhodium(I) Hydride
- Tris(triphenylphosphine)rhodium(I) Carbonyl Hydride
Product Documents:
| Size | Unit Price | Shanghai | Tianjin | Japan* |
|---|---|---|---|---|
| 250MG |
¥620.00
|
13 | Contact Us | Contact Us |
| 1G |
¥1,990.00
|
1 | 1 | 4 |
| 5G |
¥6,565.00
|
4 | 2 | 17 |
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| Product Number | C1383 |
| Molecular Formula / Molecular Weight | C__5__5H__4__6OP__3Rh = 918.80 |
| Physical State (20 deg.C) | Solid |
Storage Temperature 
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Moisture Sensitive |
| Packaging and Container
|
1G-Glass Bottle with Plastic Insert (View image), 250MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 17185-29-4 |
| PubChem Substance ID | 87566394 |
| SDBS (AIST Spectral DB) | 39303 |
| Merck Index (14) | 9758 |
| MDL Number | MFCD00151644 |
Specifications
| Appearance | Light yellow to Yellow powder to crystal |
| Elemental analysis(Carbon) | 70.50 to 72.60 % |
Properties (reference)
| Melting Point | 122 °C(dec.) |
| Solubility (soluble in) | Chloroform, dichloromethane, Benzene |
GHS
| Hazard Statements | H413 : May cause long lasting harmful effects to aquatic life. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. |
Related Laws:
Transport Information:
| Customs Control Conditions (Q) |
Application
Rh(I)-catalyzed synthesis of indoles through the amino-Claisen rearrangement of N-propargylanilines
Typical procedure: Under an argon atmosphere, to a solution of carbonyltris(triphenylphosphine)rhodium(I) hydride (16 micro-mol) in 1,1,1,3,3,3-hexafluoro-2-propanol (1 mL) is added N-2-butynyl-N-benzyl-4-methoxyaniline (0.4 mmol) in 1,1,1,3,3,3-hexafluoro-2-propanol (1.5 mL) at an ambient temperature, and the mixture is refluxed until the consumption of the substrate by TLC analysis. The mixture is diluted with ether and filtered through a Celite pad. After concentration of the filtrate to dryness, purification by silica gel chromatography (hexane/AcOEt = 25:1) gives the corresponding indole in 99% yield.
References
PubMed Literature
Product Documents (Note: Some products will not have analytical charts available.)
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