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CAS RN: 78489-65-3 | Product Number: E1200

Ethyl α-Iodophenylacetate


Purity: >97.0%(T)(HPLC)
Synonyms:
  • α-Iodophenylacetic Acid Ethyl Ester
  • Ethyl 2-Iodo-2-phenylacetate
  • 2-Iodo-2-phenylacetic Acid Ethyl Ester
Documents:
5G
₹4,000
2   2   ≥20 
25G
₹13,800
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Product Number E1200
Purity / Analysis Method >97.0%(T)(HPLC)
Molecular Formula / Molecular Weight C__1__0H__1__1IO__2 = 290.10  
Physical State (20 deg.C) Liquid
Storage Temperature <0°C
Condition to Avoid Light Sensitive,Heat Sensitive
CAS RN 78489-65-3
Reaxys Registry Number 6859197
PubChem Substance ID 354333819
Specifications
Appearance Light yellow to Brown clear liquid
Purity(HPLC) min. 97.0 area%
Purity(Argentmetric Titration) min. 97.0 %
Specific gravity (20/20) 1.5630 to 1.5680
Refractive index n20/D 1.5780 to 1.5820
Properties (reference)
Flash point 137 °C
Specific Gravity (20/20) 1.57
Refractive Index 1.58
GHS
Pictogram Pictogram
Signal Word Danger
Hazard Statements H314 : Causes severe skin burns and eye damage.
H290 : May be corrosive to metals.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P234 : Keep only in original container.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P390 : Absorb spillage to prevent material damage.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P406 : Store in corrosive resistant container with a resistant inner liner.
P405 : Store locked up.
Related Laws:
Transport Information:
UN Number UN3265
Class 8
Packing Group II
Application
Alkyl Iodide Initiators for Organocatalyzed Living Radical Polymerization

General Scheme of Organocatalyzed Living Radical Polymerization1-4)

Goto et al. have reported that alkyl iodides are efficient initiators for organocatalyzed living radical polymerization which is a new family of living radical polymerization. Organic amines and organic salts are used as catalysts.1-4) Low polydispersity and metal free polymers can be obtained by using this method.
Ranges of Effective Alkyl Iodides in the Polymerizations of Methyl Methacrylate (MMA) and Butyl Acrylate (BA)1)

These alkyl iodides are effective initiators in methyl methacrylate (MMA) [M0087] and butyl acrylate (BA) [A0142] polymerizations using tributylmethylphosphonium iodide (BMPI) [M1455] or tetrabutylammonium iodide (BNI) [T0057] as a catalyst. Low-polydispersity polymers are obtainable.1)

References


PubMed Literature


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