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Optically Active Ketoiminato Co(II) Complexes for Enantioselective Borohydride Reduction
No.126(August 2007)
The ketoiminato cobalt(II) complexes 1 and 2 developed by Mukaiyama, Yamada and co-workers are utilized for catalytic asymmetric reductions. The asymmetric reduction using 1 and 2 can use sodium borohydride, a widely used reducing agent. Therefore, this method is receiving much attention as it is likely to become a popular, convenient and economical method for obtaining optically active alcohols, amines, 1,3-diols, 3-hydroxycarbonyl compounds, β-substituted amides and so forth.
References
- 1)Applications of MPAC
- K. D. Sugi, T. Nagata, T. Yamada, T. Mukaiyama, Chem. Lett. 1997, 26, 493.
- S. Kezuka, T. Mita, N. Ohtsuki, T. Ikeno, T. Yamada, Chem. Lett. 2000, 29, 824.
- T. Mukaiyama, K. D. Sugi, T. Nagata, T. Yamada, WO 98039276 (Mitsui Chemicals Inc.).
- K. D. Sugi, T. Nagata, T. Yamada, T. Mukaiyama, Chem. Lett. 1997, 26, 493.
- 2)Applications of AMAC
- Y. Ohtsuka, K. Koyasu, T. Ikeno, T. Yamada, Org. Lett. 2001, 3, 2543.
- Y. Ohtsuka, K. Koyasu, D. Miyazaki, T. Ikeno, T. Yamada, Org. Lett. 2001, 3, 3421.
- M. Sato, Y. Gunji, T. Ikeno, T. Yamada, Synthesis 2004, 1434.
- T. Nagata, T. Yamada, WO 02038535 (Mitsui Chemicals Inc.).
- Y. Ohtsuka, K. Koyasu, T. Ikeno, T. Yamada, Org. Lett. 2001, 3, 2543.
- 3)Reviews
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