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CAS RN: 434937-12-9 | Product Number: C2421

1-(Cyanomethyl)piperidinium Tetrafluoroborate


Purity: >98.0%(N)
Synonyms:
Documents:
5G
$114.00
2   2   10  

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Product Number C2421
Purity / Analysis Method >98.0%(N)
Molecular Formula / Molecular Weight C__7H__1__3BF__4N__2 = 212.00 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 434937-12-9
Reaxys Registry Number 9533187
PubChem Substance ID 125307530
Specifications
Appearance White to Almost white powder to crystal
Purity(with Total Nitrogen) min. 98.0 %
Melting point 103.0 to 107.0 °C
Properties (reference)
Melting Point 105 °C
GHS
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled.
H314 : Causes severe skin burns and eye damage.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P260 : Do not breathe dusts or mists.
P270 : Do not eat, drink or smoke when using this product.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P405 : Store locked up.
Related Laws:
Transport Information:
UN Number (DOT-AIR) UN1759
Class (DOT-AIR) 8
Packing Group (TCI-A) III
HS Number 2933.39.9200
Application
A Useful Condensation Activator Bearing Less Nucleophilicity and No Deliquescence

Wada et al. developed 1-(cyanomethyl)piperidinium tetrafluoroborate (1) conjugates, with a highly less nucleophilic counteranion, BF4-.1) It has appropriate proton-donating ability as a condensation activator to give the corresponding dinucleotide without any loss of the diastereopurity. In addition, the activator has no deliquescence and good solubility in CH3CN. Therefore, the activator can be broadly applicable to condensation reactions.

References


PubMed Literature


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