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CAS RN: 3945-69-5 | Product Number: D2919

4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium Chloride


Purity: >95.0%(HPLC)
Synonyms:
  • DMTMM
Documents:
5G
$98.00
14   5   ≥100 
25G
$280.00
3   Contact Us ≥100 

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Product Number D2919
Purity / Analysis Method >95.0%(HPLC)
Molecular Formula / Molecular Weight C__1__0H__1__7ClN__4O__3 = 276.72 
Physical State (20 deg.C) Solid
Storage Temperature Frozen (<0°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Hygroscopic,Heat Sensitive
CAS RN 3945-69-5
Reaxys Registry Number 8026872
PubChem Substance ID 87560457
MDL Number

MFCD03613550

Specifications
Appearance White to Almost white powder to crystal
Purity(HPLC) min. 95.0 area%
Purity(with Total Nitrogen) min. 98.0 %(calcd.on dried substance)   
Drying loss max. 17.0 %
Properties (reference)
Solubility (soluble in) Methanol
GHS
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H302 : Harmful if swallowed.
H314 : Causes severe skin burns and eye damage.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P260 : Do not breathe dusts or mists.
P270 : Do not eat, drink or smoke when using this product.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P405 : Store locked up.
Related Laws:
Transport Information:
UN Number (DOT-AIR) UN3261
Class (DOT-AIR) 8
Packing Group (TCI-A) II
HS Number 2933.69.6050
Application
TCI Practical Example: DMTMM-mediated Condensation

Used Chemicals

Procedure

To a solution of 3-phenylpropionic Acid (1.80 g, 12.0 mmol) and 2-phenylethylamine (1.60 g, 13.2 mmol) in MeOH (120 mL) was added DMTMM (3.65 g, 13.2 mmol) and the mixture was stirred at room temperature for 1 hour. The solvent was removed under reduced pressure. Saturated aqueous sodium bicarbonate solution (100 mL) was added to the residue. After being stirred for 10 minutes, the mixture was extracted with diethyl ether (100 mL). The separated organic layer was washed with deionized water (50 mL), 1 mol/L hydrochloric acid (50 mL), deionized water (50 mL) and brine (100 mL), dried over magnesium sulfate and filtered. The solvent was removed under reduced pressure and the residue was purified by column chromatography (2:1 ethyl acetate / hexane on SiO2), giving white solid (2.54 g, 84%).

Experimenter’s Comments

The reaction mixture was monitored by TLC (hexane : ethyl acetate = 1 : 1, Rf = 0.30) and GC.

Analytical Data (N-Phenylethyl-3-phenylpropaneamide)

1H NMR (400 MHz, CDCl3); δ 7.05–7.28 (m, 10H), 5.31 (br s, 1H), 3.46 (q, J = 6.8 Hz, 2H), 2.92 (t, J = 7.6 Hz, 2H), 2.71 (t, J = 6.8 Hz, 2H), 2.40 (t, J = 7.6 Hz, 2H).

13C NMR (101 MHz, CDCl3); δ 172.0, 140.8, 138.8, 128.7 (2C), 128.6, 128.5, 128.3, 126.4, 126.2, 40.5, 38.5, 35.6, 31.6.

Lead Reference

Other References


PubMed Literature


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