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CAS RN: 1271-66-5 | Product Number: D4100
Dimethyltitanocene (5% in Tetrahydrofuran/Toluene)
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|Molecular Formula / Molecular Weight||C__1__2H__1__6Ti = 208.13|
|Physical State (20 deg.C)||Liquid|
|Store Under Inert Gas||Store under inert gas|
|Condition to Avoid||Moisture Sensitive,Heat Sensitive|
|Reaxys Registry Number||14221496|
|PubChem Substance ID||135727045|
|Appearance||Orange to Red clear liquid|
|Concentration(HNMR)||5.0 to 5.7 w/w%|
|Specific Gravity (20/20)||0.89|
|Hazard Statements||H332 : Harmful if inhaled.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H360 : May damage fertility or the unborn child.
H370 : Causes damage to organs.
H372 : Causes damage to organs through prolonged or repeated exposure.
H351 : Suspected of causing cancer.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
H304 : May be fatal if swallowed and enters airways.
H401 : Toxic to aquatic life.
H225 : Highly flammable liquid and vapor.
|Precautionary Statements||P501 : Dispose of contents/ container to an approved waste disposal plant.
P273 : Avoid release to the environment.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P202 : Do not handle until all safety precautions have been read and understood.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P201 : Obtain special instructions before use.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P331 : Do NOT induce vomiting.
P307 + P311 : IF exposed: Call a POISON CENTER or doctor/ physician.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P362 : Take off contaminated clothing and wash before reuse.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 : Store in a well-ventilated place. Keep cool.
P405 : Store locked up.
|UN Number (DOT-AIR)||UN1993|
|Packing Group (TCI-A)||II|
- N. A. Petasis, E. I. Bzowej, J. Am. Chem. Soc. 1990, 112, 6392.
- N. A. Petasis, S.-P. Lu, E. I. Bzowej, D.-K. Fu, J. P. Staszewski, I. Akritopoulou-Zanze, M. A. Patane, Y.-H. Hu, Pure Appl. Chem. 1996, 68, 667.
- Olefin Metathesis in Cyclic Ether Formation. Direct Conversion of Olefinic Esters to Cyclic Enol Ethers with Tebbe-Type Reagents
Safety Data Sheet (SDS)
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