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CAS RN: 502964-52-5 | Product Number: N1060

nitro-Grela


Purity: >97.0%(HPLC)
Synonyms:
  • [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[(2-isopropoxy-5-nitrobenzylidene)]ruthenium(II)
Documents:
100MG
$217.00
1   8   ≥20 
500MG
$650.00
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Sold in collaboration with Apeiron Synthesis.
PCT/EP2003/011222

Product Number N1060
Purity / Analysis Method >97.0%(HPLC)
Molecular Formula / Molecular Weight C__3__1H__3__7Cl__2N__3O__3Ru = 671.63  
Physical State (20 deg.C) Solid
CAS RN 502964-52-5
Reaxys Registry Number 19324055
PubChem Substance ID 354334037
MDL Number

MFCD28411645

Specifications
Appearance Green to Dark green powder to crystal
Purity(HPLC) min. 97.0 area%
Elemental analysis(Nitrogen) 5.90 to 6.50 %
Properties (reference)
GHS
Related Laws:
Transport Information:
HS Number 2931.90.6000
Application
Nitro-Grela: A Metathesis Catalyst Applicable to Macrocycle construction

References


Application
Nitro-Grela: A Metathesis Catalyst Applicable to Various Substrates

References


Application
メタセシス反応に有用なルテニウム錯体,ニトロ-グレラ

Experimental procedure2): A mixture of 1 (25.0 mg, 69.3 µmol) and nitro-Grela (929 µg, 1.39 µmol) in CH2Cl2 (3.5 mL) is stirred at room temperature for 2 h. The mixture is concentrated to give a residue, which is subjected to column chromatography on silica gel. Elution with hexane:ethyl acetate (10:1) gives 2 (15.6 mg, 74% yield) as a colorless oil.

References


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