Published TCIMAIL newest issue No.191 | [Product Highlights] ShoyakuGreen, a Fluorescent Dye for Staining... | Various analytical charts can be searched on each product detail page and Product Document Search (The kinds of analytical charts differ by product)
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 1414707-08-6 | Product Number: A3009
AquaMet
×
![]()
×
Purity: >95.0%(HPLC)
Synonyms:
- [1,3-Bis(2,4,6-trimethylphenyl)-4-[(4-ethyl-4-methylpiperazinium-1-yl)methyl]-2-imidazolidinylidene]dichloro(2-isopropoxybenzylidene)ruthenium(II) Chloride
Documents:
| Size | Unit Price | Hyderabad | Japan* | Quantity |
|---|---|---|---|---|
| 100MG |
₹7,400
|
Contact Us | 23 |
|
| 500MG |
₹30,600
|
2 | 7 |
|
*Upon orders receipt, Hyderabad stocks will be dispatched on the same day.
*Items available in Japan warehouse will be dispatched in 10-12 working days.
*INR price is exclusive of domestic taxes applicable.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Note:
Sold in collaboration with Apeiron Synthesis.
PCT/EP2013/053967
| Product Number | A3009 |
| Purity / Analysis Method | >95.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__3__9H__5__5Cl__3N__4ORu = 803.32 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | 0-10°C |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Hygroscopic,Heat Sensitive |
| Packaging and Container | 500MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 1414707-08-6 |
| Reaxys Registry Number | 27464286 |
| PubChem Substance ID | 354334182 |
| MDL Number | MFCD28411647 |
Specifications
| Appearance | Light yellow to Amber to Dark green powder to crystal |
| Purity(HPLC) | min. 95.0 area% |
Properties (reference)
GHS
Related Laws:
Transport Information:
Application
TCI Practical Example: Olefin Metathesis
Used Chemicals
- Diethyl Diallylmalonate [D1183]
- AquaMet [A3009]
- Dichloromethane
Procedure
-
In a 200 mL two necked round bottomed flask, AquaMet (50 mg, 52 μmol) was added, and purged with N2. Dichloromethane (100 mL) was charged in the flask, and diethyl diallylmalonate (500 mg, 2.08 mmol) in dichloromethane (20 mL) was added dropwise and the mixture was stirred at room temperature for 6 h. The solvent was removed under reduced pressure and the residue was purified by silica-gel column chromatography (hexane : EtOAc = 1 : 1) to give diethyl cyclopent-3-ene-1,1-dicarboxylate as a pale yellow oil (430 mg, 98%).
Experimenter's Comments
The reaction mixture was monitored by NMR.
Analytical Data（Diethyl cyclopent-3-ene-1,1-dicarboxylate）
1H NMR (400 MHz, CDCl3); δ 5.61 (s, 2H), 4.20 (q, J = 8.0 Hz, 4H), 3.01 (s, 4H), 1.25 (t, J = 8.0 Hz, 6H).
Lead Reference
- Nitro-Substituted Hoveyda−Grubbs Ruthenium Carbenes: Enhancement of Catalyst Activity through Electronic Activation
Application
Metathesis Catalyst Usable in Water Media
Flask equipped with a magnetic stirring bar is charged with Z-olefin (8.7 mg, 0.15 mmol) and non-degassed D2O (1.5 ml). Next to this solution AquaMet (0.6 mg, 0.75 µmol) is added. Reaction mixture is stirred at 25 °C for 1.1 h. Next 0.7 ml of reaction mixture is transferred to an NMR tube. Yield of a product (71%) is determined using NMR method.
References
- Highly active catalysts for olefin metathesis in water
Application
Ring Closing Metathesis in Water Media
References
- Highly active catalysts for olefin metathesis in water
Application
Mesoporous Silica Supported Metathesis Catalyst
References
- Ru-based complexes with quaternary ammonium tag immobilized on mesoporous silica as olefin metathesis catalysts
Articles/Brochures
TCIMAIL
[Product Highlights] Metathesis Catalyst Usable in Water Media[TCI Practical Example] Olefin Metathesis with AquaMet
Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number is entered
Analytical Charts
Please enter Lot Number
Incorrect Lot Number is entered
The requested analytical chart is not available. Sorry for the inconvenience.