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CAS RN: 1414707-08-6 | Product Number: A3009

AquaMet


Purity: >95.0%(HPLC)
Synonyms:
  • [1,3-Bis(2,4,6-trimethylphenyl)-4-[(4-ethyl-4-methylpiperazinium-1-yl)methyl]-2-imidazolidinylidene]dichloro(2-isopropoxybenzylidene)ruthenium(II) Chloride
Documents:
100MG
$273.00
3   3   5  
500MG
$819.00
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Sold in collaboration with Apeiron Synthesis.
PCT/EP2013/053967

Product Number A3009
Purity / Analysis Method >95.0%(HPLC)
Molecular Formula / Molecular Weight C__3__9H__5__5Cl__3N__4ORu = 803.32  
Physical State (20 deg.C) Solid
Storage Temperature 0-10°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Hygroscopic,Heat Sensitive
CAS RN 1414707-08-6
Reaxys Registry Number 27464286
PubChem Substance ID 354334182
MDL Number

MFCD28411647

Specifications
Appearance Light yellow to Amber to Dark green powder to crystal
Purity(HPLC) min. 95.0 area%
Elemental analysis(Nitrogen) 6.50 to 7.50 %
Properties (reference)
GHS
Related Laws:
Transport Information:
HS Number 2933.29.4300
Application
Metathesis Catalyst Usable in Water Media

Flask equipped with a magnetic stirring bar is charged with Z-olefin (8.7 mg, 0.15 mmol) and non-degassed D2O (1.5 ml). Next to this solution AquaMet (0.6 mg, 0.75 µmol) is added. Reaction mixture is stirred at 25 °C for 1.1 h. Next 0.7 ml of reaction mixture is transferred to an NMR tube. Yield of a product (71%) is determined using NMR method.

References


Application
Ring Closing Metathesis in Water Media
References

Highly active catalysts for olefin metathesis in water

K. Skowerski, G. Szczepaniak, C. Wierzbicka, Ł. Gułajski, M. Bieniek, K. Grela, Catal. Sci. Technol. 2012, 2424.


Application
Mesoporous Silica Supported Metathesis Catalyst
References

Ru-based complexes with quaternary ammonium tag immobilized on mesoporous silica as olefin metathesis catalysts

J. Pastva, K. Skowerski, S. J. Czarnocki, N. Žilková, J. Čejka, Z. Bastl, H. Balcar, ACS Catal. 2014, 4, 3227.


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