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CAS RN: 894102-11-5 | Product Number: B3354
Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide
![Chemical Structure of Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide](/medias/B3354.jpg?context=bWFzdGVyfHJvb3R8NTUxNzR8aW1hZ2UvanBlZ3xhRGMwTDJnMU55ODRPVEl3TVRFME9USXhOVEF5TDBJek16VTBMbXB3Wnd8OWNlYjllMzY3NDI0ODRkN2YyNzQ2Mzg0NjBmNDUyMTFiZTVhNjU1OTA5YjlkODMxNjU4YzQ1ZTFhNTc5NWUyNQ "Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide")
![Thumbnail of Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide](/medias/B3354.jpg?context=bWFzdGVyfHJvb3R8MTc1MTN8aW1hZ2UvanBlZ3xhRFkzTDJnME15ODRPVE16TlRrME1qTTBPVEV3TDBJek16VTBMbXB3Wnd8MzUxZDE1MzliNGQ4NTdjM2I4MTQ2ODRjZjFkMjVjYjc3NjZhMWQ0NjU2ZWJkZDlhNzJkN2Q4ZWIwMDNiNjY1Yw)
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![Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide")
Purity: >98.0%(T)(N)
Synonyms:
Product Documents:
| Size | Unit Price | Hyderabad | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
₹8,400.00
|
Contact Us | 5 |
|
*Upon orders receipt, Hyderabad stocks will be dispatched on the same day.
*Items available in Japan warehouse will be dispatched in 10-12 working days.
*INR price is exclusive of domestic taxes applicable.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | B3354 |
Purity / Analysis Method 
|
>98.0%(T)(N) |
| Molecular Formula / Molecular Weight | C__1__3H__1__3Br__2N__5Ni = 457.78 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| CAS RN | 894102-11-5 |
| PubChem Substance ID | 87561048 |
Specifications
| Appearance | Orange to Amber to Dark red powder to crystal |
| Purity(with Total Nitrogen) | min. 98.0 % |
| Purity(Chelometric Titration) | min. 98.0 % |
| NMR | confirm to structure |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350 : May cause cancer. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P272 : Contaminated work clothing should not be allowed out of the workplace. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P201 : Obtain special instructions before use. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P304 + P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P405 : Store locked up. |
Related Laws:
Transport Information:
Application
Kumada-Tamao-Corriu Cross-Coupling Reaction
References
- Catalytic Activities of a Bis(carbene)-Derived Nickel(II)-Pincer Complex in Kumada-Tamao-Corriu and Suzuki-Miyaura Coupling Reactions for the Synthesis of Biaryl Compounds
Application
Suzuki-Miyaura Cross-Coupling Reaction
References
- Synthesis and Catalytic Activity of a Pincer-Type Bis(imidazolin-2-ylidene) Nickel(II) Complex
Documents
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
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Analytical Charts
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